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  • 1.  Ethnographic Object Treated with Mercury

    Posted 06-13-2019 22:41
    I have a beaded leather pouch that was offered to us as a donation.  We accepted the bag as an incoming loan so we could research whether or not we wanted to acquire the piece.  During this time an XRF test was done using a portable unit, and the bag tested positive for mercury and lead (the presence of arsenic was indeterminate due to limitations of the XRF unit).  Our policy is to err on the side of caution and treat any item with the presence of heavy metals as hazardous; with all that entails, we decided not to accept the piece.

    I contacted the donor to let him know we wouldn't be accepting the piece and to inform him of the presence of heavy metals on the bag.  I let him know the test only confirms the presence of these metals and not the quantity, so I couldn't speak to the exact risks they posed.  This information freaked him out a bit.  He doesn't want the pouch around his home given the hazards and doesn't feel he can sell it to a collector or pass it on to another person to make it their hazard; he even suggested I bury the bag if it's the right thing to do (!). 

    I would like to point him in the right direction for information so he can make an informed decision.  Any knowledge you have or references I can share with him would be appreciated!

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    Rhonda Brewer
    Museum Curator
    Pecos National Historical Park
    Pecos, New Mexico
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  • 2.  RE: Ethnographic Object Treated with Mercury

    Posted 06-14-2019 11:59
    Hi Rhonda, this is a timely and excellent question for which there is no clear answer. It's easy to over-react. You might point the owner to this volume which can be downloaded free https://opensi.si.edu/index.php/smithsonian/catalog/book/64 Although this might be too much information - you could look at the references inside the volume to recommend something less daunting. This might be a little easier http://www.spnhc.org/media/assets/cofo_2001_V17N12.pdf , or Nancy Odegaard's book Odegaard, Nancy, et. al. 2005. Old Poisons, New Problems. Walnut Creek, CA: Alta Mira Press.
    other resources:
    https://www.doi.gov/sites/doi.gov/files/migrated/museum/upload/Contaminated_Collections_FAQs.pdf 
    https://www.amnh.org/research/natural-science-collections-conservation/general-conservation/health-safety/residual-pesticides

    I was just speaking with colleagues at Smithsonian Natural History Repatriation about the difficulty of communicating possible hazards to tribal members. I know they were working with the EPA as Smithsonian industrial hygienists. Typically we suggest people use PPE (gloves) when handling "contaminated" items, consult a medical toxicologist,  and colloquially say "don't eat it or lick it". 

    Was there there any red pigment (i.e. cinnabar/vermilion HgS) on the bag?

    Good luck!
    Emily

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    Emily Kaplan
    Objects Conservator
    National Museum of the American Indian
    Washington DC
    (301) 238-1418
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  • 3.  RE: Ethnographic Object Treated with Mercury

    Posted 06-15-2019 15:36
    Thanks, Emily.

    No residue or red pigment was found on the bag.  I provided the owner with general guidelines for handling the bag which included wearing non-cotton gloves and protective clothing, working in a well-ventilated space, and not touching one's face while handling the object.  

    If appropriate, I would like to be able to tell him that the bag could be displayed in a sealed frame/case (it had been on display in an unsealed frame prior to us receiving it on loan).  Considering liability issues, perhaps I should tell him a sealed display is an option but that he should consult with a medical toxicologist first (?).

    Ethnographic items are bought and sold all the time; does anyone know how antique dealers and auction houses address this issue?  (Or maybe they don't.)

    Rhonda




    ------Original Message------

    Hi Rhonda, this is a timely and excellent question for which there is no clear answer. It's easy to over-react. You might point the owner to this volume which can be downloaded free https://opensi.si.edu/index.php/smithsonian/catalog/book/64 Although this might be too much information - you could look at the references inside the volume to recommend something less daunting. This might be a little easier http://www.spnhc.org/media/assets/cofo_2001_V17N12.pdf , or Nancy Odegaard's book Odegaard, Nancy, et. al. 2005. Old Poisons, New Problems. Walnut Creek, CA: Alta Mira Press.
    other resources:
    https://www.doi.gov/sites/doi.gov/files/migrated/museum/upload/Contaminated_Collections_FAQs.pdf 
    https://www.amnh.org/research/natural-science-collections-conservation/general-conservation/health-safety/residual-pesticides

    I was just speaking with colleagues at Smithsonian Natural History Repatriation about the difficulty of communicating possible hazards to tribal members. I know they were working with the EPA as Smithsonian industrial hygienists. Typically we suggest people use PPE (gloves) when handling "contaminated" items, consult a medical toxicologist,  and colloquially say "don't eat it or lick it". 

    Was there there any red pigment (i.e. cinnabar/vermilion HgS) on the bag?

    Good luck!
    Emily

    ------------------------------
    Emily Kaplan
    Objects Conservator
    National Museum of the American Indian
    Washington DC
    (301) 238-1418
    ------------------------------


  • 4.  RE: Ethnographic Object Treated with Mercury

    Posted 06-17-2019 13:03
    One concern about mercury-containing materials is that all forms of inorganic mercury off-gas mercury vapor, even when bound to an organic substrate. This need not be a problem if the object is handled in a well-ventilated environment (mercury vapor tends to move to the floor and dissipate rapidly). However, it is a concern when objects are kept in closed environment and the vapor can accumulate. Having well designed protocols for opening cabinets or other containers and allowing them to vent, or moving closed packages to a local exhaust ventilation hood to vent them can be simple, but very effective.

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    Catharine Hawks
    Museum Conservator
    National Museum of Natural History
    703-200-4370
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  • 5.  RE: Ethnographic Object Treated with Mercury

    Posted 06-14-2019 11:59
      |   view attached
    Hi Rhonda, 

    I am the C2C Care monitor for this week and am reaching out to others to find an answer for you.

    In the mean time, I have attached a resources list from a 2016 C2C webinar entitled Arsenic and Lace: Controlling Hazardous Collection Material
    https://www.connectingtocollections.org/arsenic-and-old-lace-controlling-hazardous-collection-materials/


    Best, 
    Maddie

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    Madeline Cooper
    Graduate Fellow
    Winterthur/University of Delaware Program in Art Conservation
    Wilmington, DE

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