Archaeological Discussion Group

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  • 1.  Adhesives for hot climates

    Posted 09-03-2023 18:35

    Dear Archaeo-colleagues,

    I know this is a hot topic (pun intended!) but what are your favorite adhesives for joining ceramics (and maybe small stone objects) in a climate that tops that magic number of 40C? 

    Many thanks for sharing your current winners,

    Nina



    ------------------------------
    Nina Owczarek
    Assistant Professor
    University of Delaware Art Conservation Department
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  • 2.  RE: Adhesives for hot climates

    Posted 09-04-2023 09:44

    Dear Nina Owczarek

    I have seen the use of Mowital B 60HH (Polyvinyl butyral PVB) dissolved in alcohol as an adhesive in cases of climatic conditions where the temperature exceeds 40°C.

    Link to the product

    This polymer is undoubtedly more durable and resilient than Paraloid B72, but this significantly reduces its reversibility.

    In the past, I had to disassemble artifacts glued with this polymer, and I encountered significant difficulties so I'm not sure if I would recommend it, but in cases of high-temperature requirements, I believe it's the most commonly used product here.



    ------------------------------
    Simone Morbin
    Conservator
    Freelance/Private Practice/Self-employed/Independent
    Belluno
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  • 3.  RE: Adhesives for hot climates

    Posted 09-04-2023 20:44

    Hi Nina,

    A shout out to our AIC and OSG leadership @Suzanne Davis and @Caroline Roberts for their recent publication in Studies in Conservation where they discuss their approach to this issue: 

    Suzanne L. Davis, Caroline Roberts & Andrea Poli (2022) Paraloid®B-72/B-48N 1:1 as an Adhesive for Use in Hot Climates: Literature Review, Laboratory
    Testing, and Observational Field Study, Study, Studies in Conservation, 67:6, 357-365, DOI:10.1080/00393630.2021.1891810

    This was brought to my attention at the recent ICOM CC Glass & Ceramics conference. My students at NYU this past term had great success joining archaeological glass with this blend. (The artifacts are destined for an enclosed display case in a non-climate controlled stairwell with a glass dome in Beirut, and we are hopeful the blend will hold up to the fluctuations there...)

    I recently became aware of Mowital B 60HH in use on excavations in Italy, so my colleague has just acquired some for her students to compare with B72 as an experiment this coming term. You can only buy it by the kilo, so if you are interested, we have enough in our lab to supply the entire East Coast for years to come..... I know she and her students would be very curious to hear about others' experience with it (thanks Simone for chiming in about the challenges you've experienced reversing it).

    Best,

    Rebecca



    ------------------------------
    Rebecca Gridley
    Associate Conservator
    Art Conservation Group
    Long Island City, NY
    rebecca.ec.gridley@gmail.com
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  • 4.  RE: Adhesives for hot climates

    Posted 09-05-2023 12:43

    Since nobody's said this yet, I'll just comment that I know I'm not the only conservator who feels that although pure B48N may have a high enough Tg for 40+ C storage situations, like Mowital B 60HH, it just isn't as reversible as you'd think it should be. (I do use B48N in combination with B72 and have had less slumping problems so far, even though all the testing I know about indicates that mixing B72 with B48N doesn't really raise the Tg that much). Rebecca, I'll be interested to know the results of your students' experimentation.



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    Julie Unruh
    Austin TX
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  • 5.  RE: Adhesives for hot climates

    Posted 09-06-2023 08:59

    In 2017 at AIC's OSG session I presented on Israel's choice of Mowital B60HH which is the adhesive primarily used by Israel's Antiquities Authority for ceramic reconstruction. Their choice was primarily influenced by the recommendations of the Italian Istituto Centrale  per il Resauro (ICR).  I have to say that I liked its working properties but I won't disagree with Julie's assessment of its reversibility. At the IAA they use (or at least were using) B72 for consolidation but not for reconstruction.



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    Rachael Arenstein
    A.M. Art Conservation, LLC
    rachael@amartconservation.com
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  • 6.  RE: Adhesives for hot climates

    Posted 09-06-2023 10:53
    The research, experiences, and reasoning for these choices is interesting and helpful. Thanks to all who have offered thoughts so far. This is such a smart and generous group!!
    Warmly,
    Nina

    ---
    Nina Owczarek 
    she/her/hers
    Assistant Professor, Art Conservation 
    University of Delaware
    305 Old College







  • 7.  RE: Adhesives for hot climates

    Posted 09-10-2023 23:43

    I'm wondering about the techniques you used to work with the Mowital B60HH? We tried it here but found it not very easy to work with as an adhesive, because it has no tack. 



    ------------------------------
    Kathy Hall
    Senior Conservator
    INSTAP Study Center for East Crete
    Crete
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  • 8.  RE: Adhesives for hot climates

    Posted 09-06-2023 10:51
    Hi! Thanks for the shout-out Rebecca! We are pretty proud of that paper - I think it's one of the best pieces of writing we've done, which may sound weird, but we took a lot of care to make sure it was clear. If anyone would like a copy, let me know and I'll send you a pdf. If you have access to Taylor and Francis online, like through a university library, you can also download it from there. 

    We found that Tg moved exactly like you would expect it to when mixing B:72 and B:48N. If you mix them 1:1, for example, it moves halfway between. But we also found - and this is the key takeaway - that the temperature conservators truly need to care about is the onset temperature of the glass transition. It's not the Tg as it's usually reported in product literature for adhesives - what's usually reported is the midpoint of the transition. 

    We have other practical takeaways in the paper, e.g. to help you deal with storage of glued things in hot climates, and we include a good lit review for this topic, but our main advice is that the onset temperature is what you need to pay attention to and, unfortunately, this is not usually reported so you may need to figure it out yourself. AND (take note if you are looking for research topics!), we need more adhesive creep testing in conservation.

    best,
    Suzanne
    ------------------------
    Suzanne L. Davis (she/her/hers)
    Senior Associate Curator and Head of Conservation
    University of Michigan, 434 South State Street, Ann Arbor, MI 48109-1390 USA